Natural gas

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For other uses, see Natural gas (disambiguation).

Natural gas extraction by countries in cubic meters per year.

Natural gas is a gas consisting primarily of methane, typically with 0–20% higher hydrocarbons^[1] (primarily ethane). It is found associated with other hydrocarbon fuel, in coal beds, as methane clathrates, and is an important fuel source and a major feedstock for fertilizers.
Most natural gas is created by two mechanisms: biogenic and thermogenic. Biogenic gas is created by methanogenic organisms in marshes, bogs, landfills, and shallow sediments. Deeper in the earth, at greater temperature and pressure, thermogenic gas is created from buried organic material.^[2]
Before natural gas can be used as a fuel, it must undergo processing to remove almost all materials other than methane. The by-products of that processing include ethane, propane, butanes, pentanes, and higher molecular weight hydrocarbons, elemental sulfur, carbon dioxide, water vapor, and sometimes helium and nitrogen.
Natural gas is often informally referred to as simply gas, especially when compared to other energy sources such as oil or coal.

Energy content, statistics and pricing

Energy content, statistics and pricing

Main article: Natural gas prices

Natural gas prices at the Henry Hub in US dollars per million BTUs ($/mmbtu) for 2000–2010.

Quantities of natural gas are measured in normal cubic meters (corresponding to 0 °C at 101.325 kPa) or in standard cubic feet (corresponding to 60 °F (16 °C) and 14.73 psia). The gross heat of combustion of one cubic meter of commercial quality natural gas is around 39 megajoules (≈10.8 kWh), but this can vary by several percent. This comes to about 49 megajoules (≈13.5 kWh) for one kg of natural gas (assuming 0.8 kg/m^3, an approximate value).
The price of natural gas varies greatly depending on location and type of consumer. In 2007, a price of $7 per 1,000 cubic feet (28 m³) was typical in the United States. The typical caloric value of natural gas is roughly 1,000 British thermal units (BTU) per cubic foot, depending on gas composition. This corresponds to around $7 per million BTU, or around $7 per gigajoule. In April 2008, the wholesale price was $10 per 1,000 cubic feet (28 m³) ($10/MMBTU).^[43] The residential price varies from 50% to 300% more than the wholesale price. At the end of 2007, this was $12–$16 per 1,000 cu ft (28 m³).^[44] Natural gas in the United States is traded as a futures contract on the New York Mercantile Exchange. Each contract is for 10,000 MMBTU (~10,550 gigajoules), or 10 billion BTU. Thus, if the price of gas is $10 per million BTUs on the NYMEX, the contract is worth $100,000.

Safety

Safety

A pipeline odorant injection station

A minute amount of odorant which will contain t-butyl mercaptan, with an odor that is associated with natural gas, and has been described as a rotten egg odor, is added to the otherwise colorless and almost odorless gas used by consumers, to assist in detecting leaks before a fire or explosion occurs. Sometimes a related compound, thiophane may be used in the mixture, with a rotten-egg smell. Adding odorant to natural gas began in the United States after the 1937 New London School explosion. The buildup of gas in the school went unnoticed, killing three hundred students and faculty when it ignited. Odorants are considered non-toxic in the extremely low concentrations occurring in natural gas delivered to the end user.
In mines, where methane seeping from rock formations has no odor, sensors are used, and mining apparatuses have been specifically developed to avoid ignition sources such as the Davy lamp.
Explosions caused by natural gas leaks occur a few times each year. Individual homes, small businesses and other structures are most frequently affected when an internal leak builds up gas inside the structure. Frequently, the blast will be enough to significantly damage a building but leave it standing. In these cases, the people inside tend to have minor to moderate injuries. Occasionally, the gas can collect in high enough quantities to cause a deadly explosion, disintegrating one or more buildings in the process. The gas usually dissipates readily outdoors, but can sometimes collect in dangerous quantities if flow rates are high enough. However, considering the tens of millions of structures that use the fuel, the individual risk of using natural gas is very low.
Some gas fields yield sour gas containing hydrogen sulfide (H₂S). This untreated gas is toxic. Amine gas treating, an industrial scale process which removes acidic gaseous components, is often used to remove hydrogen sulfide from natural gas.^[42]

Environmental effects

Environmental effects

See also: Environmental issues with energy

CO₂ emissions

Natural gas is often described as the cleanest fuel, producing less carbon dioxide per joule delivered than either coal or oil^[20] and far fewer pollutants than other hydrocarbon fuels. However, in absolute terms, it does contribute substantially to global carbon emissions, and this contribution is projected to grow. According to the IPCC Fourth Assessment Report (Working Group III Report, chapter 4), in 2004, natural gas produced about 5.3 billion tons a year of CO₂ emissions, while coal and oil produced 10.6 and 10.2 billion tons respectively (figure 4.4). According to an updated version of the SRES B2 emissions scenario, however, by the year 2030, natural gas would be the source of 11 billion tons a year, with coal and oil now 8.4 and 17.2 billion respectively because demand is increasing 1.9% a year^[35] (Total global emissions for 2004 were estimated at over 27,200 million tons) In addition, natural gas itself is a greenhouse gas more potent than carbon dioxide when released into the atmosphere, although natural gas is released in much smaller quantities. However, methane is oxidized in the atmosphere, and hence natural gas has a residence lifetime in the atmosphere for approximately 12 years, compared to CO₂, which is already oxidized, and has an effect for 100 to 500 years. Natural gas is mainly composed of methane, which has a radiative forcing twenty times greater than carbon dioxide. Based on such composition, a ton of methane in the atmosphere traps in as much radiation as 20 tons of carbon dioxide, but remains in the atmosphere for a 8–40 times shorter time. Carbon dioxide still receives the lion's share of attention over greenhouse gases because it is released in much larger amounts. Still, it is inevitable when natural gas is used on a large scale that some of it will leak into the atmosphere. (Coal methane not captured by coal bed methane extraction techniques is simply lost into the atmosphere; however, most methane in the atmosphere is currently from animals and bacteria, not from human's leaks.). Current estimates by the EPA place global emissions of methane at 3 trillion cubic feet annually,^[36] or 3.2% of global production.^[37] Direct emissions of methane represented 14.3% of all global anthropogenic greenhouse gas emissions in 2004.^[38]

Other pollutants

Natural gas produces far lower amounts of sulfur dioxide and nitrous oxides than any other hydrocarbon fuel.^[39] Carbon dioxide produced is 117,000 ppm vs 208,000 for burning coal. Carbon monoxide produced is 40 ppm vs 208 for burning coal. Nitrogen oxides produced is 92 ppm vs 457 for burning coal. Sulfur dioxide is 1 ppm vs 2,591 for burning coal. Mercury is 0 vs .016 for burning coal.^[40] Particulates are also a major contribution to global warming. Natural gas has 7ppm vs coal's 2,744ppm.^[41]

Storage and transport

Storage and transport

Polyethylene plastic main being placed in a trench.

Because of its low density, it is not easy to store natural gas or transport by vehicle. Natural gas pipelines are impractical across oceans. Many existing pipelines in America are close to reaching their capacity, prompting some politicians representing northern states to speak of potential shortages. In Europe, the gas pipeline network is already dense in the West.^[25] New pipelines are planned or under construction in Eastern Europe and between gas fields in Russia, Near East and Northern Africa and Western Europe. See also List of natural gas pipelines.
LNG carriers transport liquefied natural gas (LNG) across oceans, while tank trucks can carry liquefied or compressed natural gas (CNG) over shorter distances. Sea transport using CNG carrier ships that are now under development may be competitive with LNG transport in specific conditions.
Gas is turned into liquid at a liquefaction plant, and is returned to gas form at regasification plant at the terminal. Shipborne regasification equipment is also used. LNG is the preferred form for long distance, high volume transportation of natural gas, whereas pipeline is preferred for transport for distances up to 4,000 km over land and approximately half that distance offshore.
CNG is transported at high pressure, typically above 200 bars. Compressors and decompression equipment are less capital intensive and may be economical in smaller unit sizes than liquefaction/regasification plants. Natural gas trucks and carriers may transport natural gas directly to end-users, or to distribution points such as pipelines.

Peoples Gas Manlove Field natural gas storage area in Newcomb Township, Champaign County, Illinois. In the foreground (left) is one of the numerous wells for the underground storage area, with an LNG plant, and above ground storage tanks are in the background (right).

In the past, the natural gas which was recovered in the course of recovering petroleum could not be profitably sold, and was simply burned at the oil field in a process known as flaring. Flaring is now illegal in many countries.^[26] Additionally, companies now recognize that gas may be sold to consumers in the form of LNG or CNG, or through other transportation methods. The gas is now re-injected into the formation for later recovery. The re-injection also assists oil pumping by keeping underground pressures higher.

Transportation

Transportation

CNG is a cleaner alternative to other automobile fuels such as gasoline (petrol) and diesel. As of 2008 there were 9.6 million natural gas vehicles worldwide, led by Pakistan (2.0 million), Argentina (1.7 million), Brazil (1.6 million), Iran (1.0 million), and India (650,000).^[21][22] The energy efficiency is generally equal to that of gasoline engines, but lower compared with modern diesel engines. Gasoline/petrol vehicles converted to run on natural gas suffer because of the low compression ratio of their engines, resulting in a cropping of delivered power while running on natural gas (10%–15%). CNG-specific engines, however, use a higher compression ratio due to this fuel's higher octane number of 120–130.^[23]

Fertilizers

Natural gas is a major feedstock for the production of ammonia, via the Haber process, for use in fertilizer production.

Aviation

Russian aircraft manufacturer Tupolev is currently running a development program to produce LNG- and hydrogen-powered aircraft.^[24] The program has been running since the mid-1970s, and seeks to develop LNG and hydrogen variants of the Tu-204 and Tu-334 passenger aircraft, and also the Tu-330 cargo aircraft. It claims that at current market prices, an LNG-powered aircraft would cost 5,000 roubles (~ $218/ £112) less to operate per ton, roughly equivalent to 60%, with considerable reductions to carbon monoxide, hydrocarbon and nitrogen oxide emissions.

Natural gas processing

Natural gas processing

Main article: Natural gas processing

The image below is a schematic block flow diagram of a typical natural gas processing plant. It shows the various unit processes used to convert raw natural gas into sales gas pipelined to the end user markets.
The block flow diagram also shows how processing of the raw natural gas yields byproduct sulfur, byproduct ethane, and natural gas liquids (NGL) propane, butanes and natural gasoline (denoted as pentanes +).^{[15][16][17][18][19]}

Schematic flow diagram of a typical natural gas processing plant.